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Παρασκευή 3 Μαρτίου 2017

Cyclopropenone-masked dibenzocyclooctyne end-functionalized polymers from reversible addition-fragmentation chain transfer polymerization

Publication date: 7 April 2017
Source:Polymer, Volume 114
Author(s): Lin Qu, Ying Wu, Peng Sun, Ke Zhang, Zhengping Liu
Functional reversible addition-fragmentation chain transfer polymerization (RAFT) agent was developed to have a cyclopropenone-masked dibenzocyclooctyne end group. RAFT polymerization was then explored on three typical types of vinyl monomers in free radical polymerization such as styrene, methyl methacrylate, and tert-butyl acrylate. The living polymerization behaviors were demonstrated for all three cases, which guaranteed the production of well-defined polystyrene, poly (methyl methacrylate), and poly (tert-butyl acrylate) end-functionalized with cyclopropenone-masked dibenzocyclooctyne groups from the convenient RAFT polymerization technique. Under UV irradiation, the cyclopropenone-masked dibenzocyclooctyne end group could be quantitatively changed to dibenzocyclooctyne clickable group, which was widely used in the metal-free strain-promoted azide-alkyne cycloaddition (SPAAC) click reaction. Subsequently, using the dibenzocyclooctyne end-functionalized polymers as building blocks, a practical and efficient metal-free method was developed for the formation of topological polymers including block and bottlebrush polymers based on the SPAAC click reaction.

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