Characterization, kinetic, and isotherm data for Cr(VI) removal from aqueous solution by Cr(VI)-imprinted poly(4-VP-co-MMA) supported on activated Indonesia (Ende-Flores) natural zeolite structure

Publication date: Available online 2 February 2018
Source:Data in Brief
Author(s): Yantus A.B Neolaka, Ganden Supriyanto, Ni Nyoman Tri Puspaningsih, Handoko Darmokoesoemo, Heri Septya Kusuma
The adsorption performance of Cr(VI) on the Cr(VI)-imprinted poly(4-VP-co-MMA) (IIP) supported on Activated Indonesia (Ende-Flores) natural zeolite (ANZ) structure for Cr(VI) removal from aqueous solution have been studied. Cr(VI)-imprinted-poly(4-VP-co-MMA)-ANZ (IIP-ANZ) was synthesized using Cr(VI) as a template, 4-vinylphiridine (4-VP) as a complex agent, methyl methacrylate (MMA) as a monomer agent, ethylene glycol dimethylacrylate (EGDMA) as cross-linker and benzoyl peroxide (BPO) as an initiator. XRD, FTIR, SEM-EDX and BET was performed to characterize the synthesized materials. The maximum adsorption capacity was 2.431mg/g adsorbent at pH 2, contact time of 30min, under 303K respectively. Five kinetic and four isotherm models were used to find out the reaction rate of Cr(VI) adsorption processes on this adsorbent. Under the competitive condition, the adsorption capacity of this adsorbent for Cr(VI) is greater than Cr(III), Mn(II) or Ni(II) ions but it less selective if present of Pb(II) ion. Moreover, the reusability of the IIP-ANZ was tested for five times and no significant loss in adsorption capacity observed.



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