An eight-coordinate zinc complex containing the highly pre-organized ligand 1,10-phenanthroline-2,9-dicarboxylic acid: Solvothermal synthesis, supramolecular structure and CSD studies

Publication date: 5 November 2018
Source:Journal of Molecular Structure, Volume 1171
Author(s): Masoud Mirzaei, Azam Hassanpoor, Hanie Alizadeh, Mahnaz Gohari, Alexander J. Blake
A new anionic coordination complex of Zn(II) containing the highly pre-organized ligand 1,10-phenanthroline-2,9-dicarboxylate (PDA), (H3O)2[Zn(PDA)2]·2CH3NO2·2H2O·(1), has been synthesized by solvothermal methods and characterized by elemental analysis, infrared spectroscopy and single-crystal X-ray diffraction. The last of these techniques revealed a coordination sphere around Zn(II) consisting of four N atoms and four O donors from two 1,10-phenanthroline-2,9-dicarboxylate ligands which features a distorted dodecahedral geometry. The ionic coordination motifs in 1 are held together by intermolecular OH⋯O, NH⋯O and CH⋯O hydrogen bonding, CH···π and π−π stacking interactions, to produce an extended 2D architecture.

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