Processing of preceramic polymer to low density silicon carbide foam

Publication date: 15 February 2017
Source:Materials & Design, Volume 116
Author(s): Prasanta Jana, Emanuele Zera, Gian Domenico Sorarù
A method is described here for preparing lightweight and low cost polymer-derived silicon carbide foam by impregnation of preceramic polymer in polyurethane foam. A series of silicon carbide foams with various density (0.035–0.35g/cm³), porosity (87–98%) and thermal conductivity (0.05–0.12W/m·K) were prepared using allylhydropolycarbosilane as a base material. Surface analysis shows that the resultant foams have an open and interconnected porous structure. Phase analysis shows that it has cubic crystal structure. There was no evidence of cracks or damage even after treating the silicon carbide foam with concentrated hydrofluoric acid for 12days. From the oxidation resistance experiment, it can be concluded that the silicon carbide foam is stable up to 1500°C in air and 2000°C in argon.

Graphical abstract

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