Publication date: 15 June 2018
Source:Journal of Molecular Structure, Volume 1162
Author(s): Katarina Anđelković, Andrej Pevec, Sonja Grubišić, Iztok Turel, Božidar Čobeljić, Milica R. Milenković, Tanja Keškić, Dušanka Radanović
The mixed chloride-azide [ZnL(N3)1.65Cl0.35] (1) and chloride-isocyanate [CdL(NCO)1.64Cl0.36] (2) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) have been prepared and characterized by X-ray crystallography. In complexes 1 and 2, Zn1 and Cd1 ions, respectively, are five-coordinated in a distorted square based pyramidal geometry with NNO set of donor atoms of deprotonated hydrazone ligand and two monodentate ligands N3− and/or N3− and Cl− in the case of 1 and OCN− and/or OCN− and Cl− in the case of 2. The structural parameters of 1 and 2 have been discussed in relation to those of previously reported M(II) complexes with the same hydrazone ligand. Density functional theory calculations have been employed to study the interaction between the Zn2+ and Cd2+ ions and ligands. High affinity of ligands towards the Zn2+ and Cd2+ ions are predicted for both complexes.
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