Structural characterization and evaluation of municipal wastewater sludge (biosolids) from two rural wastewater treatment plants in East Texas, USA

Publication date: 5 November 2018
Source:Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Volume 204
Author(s): Kefa K. Onchoke, Christopher M. Franclemont, Paul Wayne Weatherford
Wastewater sludge (or) biosolids collected from two rural wastewater treatment plants (NWWTP, LWWTP) in East Texas, USA were characterized and evaluated via inductively coupled plasma optical emission spectrometry, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), thermogravimetric analysis, X-ray diffraction, Fourier transform infrared spectroscopy (FTIR), and ion chromatography. The proximate organic and inorganic compositions and spectroscopic characteristics of sewage sludge were determined. The results show that the concentrations of toxic metals Cd, Cr, Cu, Mo, Ni, Pb, Hg, and Zn meet USEPA guideline recommendations for land applications. Notably, metals concentrations in biosolids from NWWTP (Mn (700 ± 83) > Zn (422.5 ± 35.4 ppm) > Ba (319.5 ± 87 ppm) > Cu (240 ± 27 ppm) > B (107 ± 14 ppm) > V (24 ± 3.3 ppm) > Cr (20 ± 3.3 ppm) > Ni (16.7 ± 2.0 ppm) > Pb (16.8 ± 1.1 ppm) > As (11.99 ± 1.27 ppm) > Co (7.6 ± 0.7 ppm) > Mo (6.4 ± 1.4 ppm) > Hg (0.55 ± 0.24 ppm) > Cd (0.130 ± 0.109 ppm)) and LWWTP follow similar trends. Macro-elements concentrations in LWWTP follow the trend P (19,648 ± 169) > Fe (22,688 ± 2110) > Ca (9372 ± 163) > S (9010 ± 1009) > Al (12,538 ± 2116) > K (3514 ± 550) > Mg (33,370 ± 502) > Na (1511 ± 472). The Br⁻, NO3⁻, NO2⁻, F⁻, Cl⁻, and SO4²⁻ concentrations meet USEPA guidelines. Whereas biosolid particle sizes were in the range ~20 μm to 500 μm mineralogical results show quartz and vermiculite to be major constituents with abundancies 12.94%, and 10.87% w/wt, respectively.

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