Cu2ZnSnSSe4 solar cells with 9.6% efficiency via selenizing Cu-Zn-Sn-S precursor sputtered from a quaternary target

Publication date: January 2018
Source:Solar Energy Materials and Solar Cells, Volume 174
Author(s): Rujun Sun, Daming Zhuang, Ming Zhao, Qianming Gong, Yaowei Wei, Guoan Ren, Yixuan Wu
CZTSSe (sulfur around 1%) absorber was prepared by sputtering on a CZTS target followed by selenization under Ar carried H2Se gas. The mechanism of CZTSSe formation was investigated by Ar annealing and selenization of sputtered CZTS precursor. The apparent decomposition temperature of CZTS precursor annealed under Ar atmosphere was between 450°C and 500°C. While the temperature that CZTS precursor transformed into high-selenium CZTSSe film annealed under Ar carried H2Se gas was determined to be ≤ 400°C. CZTSSe with single-grain layer was obtained when selenization temperature exceeded 520°C. By supplying H2Se from suitable temperature, the metal components of precursor and resulting absorber were almost the same. The highest efficiency of 9.6% achieved at the optimal temperature of 560°C.

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